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Ammonium hexachloroiridate : ウィキペディア英語版 | Ammonium hexachloroiridate
Ammonium hexachloroiridate is the inorganic compound with the formula (NH4)2(). This dark brown solid is the ammonium salt of the iridium(IV) complex ()2-. It is a commercially important iridium compound.〔 It is one of the most common complexes of iridium(IV). ==Structure== The compound has been characterized by X-ray crystallography. The salt crystallizes in a cubic motif like that of ammonium hexachloroplatinate. The ()2- centers adopt octahedral molecular geometry.〔Bokii, G.B.; Ussikov, P.I. "Roentgenographische Untersuchung der Struktur des Ammonium-Chlor-Iridats (N H4)2IrCl6 Doklady Akademii Nauk SSSR 1940, vol. 26, p782-p784.〕
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